if you are using Quicktime:
pause the movie and take a screenshot (cmd + shift + 4, then select the area with the movie image).
if you are using Apple's DVD player:
download this program:
http://www.efritz.net/software.html. You click the "snap" button, then move to the DVD window, click once and then when the cursor changes you drag to select the area, release, and it's done.